Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy† †Electronic supplementary information (ESI) available: Preparation of the samples; nitrogen absorption/desorption isotherms, FT-IR spectroscopy, DNP SENS spectroscopy and DFT calculations. See DOI: 10.1039/c6sc02379g Click here for additional data file.
نویسندگان
چکیده
[a] KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal-239556900, Saudi Arabia, [b] Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland, [c] Imaging and Characterization Lab. King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia [d] Institut de Sciences Analytiques (CNRS / ENS-Lyon / UCB-Lyon 1), Université de Lyon, Centre de RMN à Très Hauts Champs, 69100 Villeurbanne, France
منابع مشابه
Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy.
Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy (DNP SENS) is an emerging technique that allows access to high-sensitivity NMR spectra from surfaces. However, DNP SENS usually requires the use of radicals as an exogenous source of polarization, which has so far limited applications for organometallic surface species to those that do not react with the radicals. Here we show that ...
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عنوان ژورنال:
دوره 8 شماره
صفحات -
تاریخ انتشار 2017